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By Carsten Bolm, F. Ekkehardt Hahn

Using secondary interactions for the activation of non-reactive substrates constitutes a brand new and sleek strategy in catalysis.
this primary entire remedy of this significant study box covers the whole box and divulges the hyperlinks among some of the chemical disciplines. It hence adopts an interdisciplinary technique, making it of curiosity to the full chemical community.
A needs to for natural, inorganic, catalytic and intricate chemists, in addition to these operating with/on organometallics.Content:
Chapter 1 Chemistry of Metalated box Molecules (pages 1–15): Berthold Kersting
Chapter 2 The Chemistry of Superbasic Guanidines (pages 17–37): Jorg Sundermeyer, Volker Raab, Ekatarina Gaoutchenova, Udo Garrelts, Nuri Abacilar and Klaus Harms
Chapter three Iron Complexes and Dioxygen Activation (pages 39–51): Thomas Nebe, Jing?Yuan Xu and Siegfried Schindler
Chapter four Tuning of buildings and homes of Bispidine Complexes (pages 53–63): Peter Comba and Marion Kerscher
Chapter five Novel Phosphorus and Nitrogen Donor Ligands Bearing Secondary Functionalities for functions in Homogeneous Catalysis (pages 65–88): Anna?Katharina Pleier, Yu sunlight, Anett Schubert, Dirk Zabel, Claudia could, Andreas Reis, Gotthelf Wolmershauser and Werner R. Thiel
Chapter 6 Square?Pyramidal Coordinated Phosphine Iron Fragments: A story of the unforeseen (pages 89–102): Andreas Grohmann and Stephan Kohl
Chapter 7 Regioselective Catalytic task of Complexes with NH, NR?Substituted Heterocyclic Carbene Ligands (pages 103–122): Siegfried R. Waldvogel, Anke Spurg and Prof. Dr. F. Ekkehardt Hahn
Chapter eight Functionalized Cycloheptatrienyl?Cyclopentadienyl Sandwich Complexes as development Blocks in Metallo?Supramolecular Chemistry (pages 123–146): Matthias Tamm
Chapter nine Monosaccharide Ligands in Organotitanium and Organozirconium Chemistry (pages 147–164): Peter Kitaev, Daniela Zeysing and Jurgen Heck
Chapter 10 Reactions of C?F Bonds with Titanocene and Zirconocene: From Secondary interplay through Bond Cleavage to Catalysis (pages 165–182): Uwe Rosenthal, Vladimir V. Burlakov, Perdita Arndt, Anke Spannenberg, Ulrike Jager?Fiedler, Marcus Klahn and Marko Hapke
Chapter eleven Bisazines within the Coordination Sphere of Early Transition Metals (pages 183–207): Ruediger Beckhaus
Chapter 12 Bifunctional Molecular structures with Pendant Bis(pentafluorophenyl)boryl teams: From Intramolecular CH?Activation to Heterolytic Dihydrogen Splitting (pages 209–230): Michael Hill, Christoph Herrmann, Patrick Spies, Gerald Kehr, Klaus Bergander, Roland Frohlich and Gerhard Erker
Chapter thirteen Ruthenium?Containing Polyoxotungstates: constitution and Redox task (pages 231–243): Ulrich Kortz
Chapter 14 From NO to Peroxide Activation by means of version Iron(III) Complexes (pages 245–272): Alicja Franke, Natalya Hessenauer?Ilicheva, Joo?Eun Jee and Rudi van Eldik
Chapter 15 man made Nitrogen Fixation with Molybdenum and Tungsten Phosphine Complexes: New advancements (pages 273–296): Gerald Stephan and Felix Tuczek
Chapter sixteen Directed C?H Functionalizations (pages 297–312): Prof. Dr. Carsten Bolm
Chapter 17 improvement of Novel Ruthenium and Iron Catalysts for Epoxidation with Hydrogen Peroxide (pages 313–337): guy relatives Tse, Bianca Bitterlich and Matthias Beller
Chapter 18 Pentacoordinating Bis(oxazoline) Ligands with Secondary Binding websites (pages 339–348): Caroline A. Schall, Michael Seitz, Anja Kaiser and Oliver Reiser
Chapter 19 Flavin Photocatalysts with Substrate Binding websites (pages 349–358): Harald Schmaderer, Jiri Svoboda and Burkhard Konig
Chapter 20 New Catalytic Cu?, Pd? and Stoichiometric Mg?, Zn?Mediated Bond Activations (pages 359–377): Tobias Thaler, Hongjun Ren, Nina Gommermann, Giuliano C. Clososki, Christoph J. Rohbogner, Stefan H. Wunderlich and Paul Knochel
Chapter 21 From Cobalt(II)?Activated Molecular Oxygen to Hydroxymethyl?Substituted Tetrahydrofurans (pages 379–396): Barbara Menendez Perez, Dominik Schuch and Jens Hartung
Chapter 22 Regiodivergent Epoxide beginning (pages 397–409): Andreas Gansauer, Florian Keller, Chun?An Fan and Peter Karbaum
Chapter 23 Supramolecular bins: Host?Guest Chemistry and Reactivity (pages 411–425): Markus Albrecht
Chapter 24 Self?Assembly of Dinuclear Helical Metallosupramolecular Coordination Compounds (pages 427–446): Ulf Kiehne, Jens Bunzen and Arne Lutzen

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B) Breslow, R. and Dong, S. Chem. , (1998) 98, 1997–2011. -N. Giorgi, M. and Reinaud, O. (2001) Journal of the American Chemical Society, 123, 8442–8443. , Goetz, S. and McKee, V. (2002) Angewandte Chemie – International Edition, 41, 4553–4556. J. J. (2000) Coordination Chemistry Reviews, 200–202, 443–485. 38 Kersting, B. (2004) Zeitschrift fur Anorganische und Allgemeine Chemie, 630, 765–780. , Fritz, T. and Hausmann, J. (1999) European Journal of Inorganic Chemistry, 2167–2172. H. and Kersting, B.

In fact, it was suggested that in hydrophobic domains of cytochrome C enzymes the guanidine functionality of arginine may bind as neutral N-donor to metal cations: this was proven for [PtCl(trpy)]þ as an artificial marker [8]. 2 Design of Superbasic Proton Sponges Since the discovery of the unusual basicity of 1,8-diaminonaphthalene (DMAN) by Alder et al. [9], the so-called ‘proton sponges’ received continuous interest from a number of research groups [10]. A proton sponge can be envisaged as the perfect chelating pincer ligand for the smallest electrophile known, the proton.

We believe that a combination of the strong donor capability, steric strain and demand will lead to unusual properties of corresponding complexes. An ongoing study is the use of TMGN and related chelating guanidines as ligands to copper(I). Cu(I) halides form nicely crystalline complexes and were tested for their catalytic ability to promote copper-catalyzed Goldberg–Buchwald type amidations of aryl halides [17]: One of the best ligands for this conversion is the secondary amine N,N0 -dimethylethylene diamine (DMEDA) with a reported yield (GC) of 67%.

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