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Additional resources for Carbohydrate Chemistry Volume 10
Bhattacharyya, K. Ramaswamy, and R. K. , 1976, 47, 167. H. M. , 1976, 46, 133. F. L. Weitl, M. Sovak, and M. Ohno, J . Medicin. , 1976, 19, 353. F. L. Weitl, M. Sovak, T. M. Williams, and J. H. Lang, J . Medicin. , 1976, 19, 1359. L. A. Carpino, H. Ringsdorf, and H. Ritter, Makromol. , 1976, 177, 1631. K. L. Matta and J. J. , 1976, 48, 65. H. G. Garg and R. W. , 1976, 49, 482. S. C. Chhabra, S. R. Gupta, C. S. Sharma, and N. D. Sharma, Indian J. , 1976, 14B, 384 (Chem. , 1976, 85, 193 025y). L.
H. Lang, J . Medicin. , 1976, 19, 1359. L. A. Carpino, H. Ringsdorf, and H. Ritter, Makromol. , 1976, 177, 1631. K. L. Matta and J. J. , 1976, 48, 65. H. G. Garg and R. W. , 1976, 49, 482. S. C. Chhabra, S. R. Gupta, C. S. Sharma, and N. D. Sharma, Indian J. , 1976, 14B, 384 (Chem. , 1976, 85, 193 025y). L. Farkas and J. Strelisky, in ‘Topics in Flavonoid Chemistry and Biochemistry’, Proceedings of the 4th Hungarian Bioflavonoid Symposium, 1973 (Pub. 1975), p. 149 (Chem. A s . , 1976, 85, 63 2942).
34 Carbohydrate Chemistry + i P 7 0 \J/ L (57) CH,OBz + I OAc HO& O y + (56) OAc Reagents : i, R1R2CO-hv-N, ; ii, R 1 R 2 C O - h ~ 0 , Scheme 18 mainly the axial oxygen atom of the dioxolan ring, yielding a derivative containing axial hydroxyl and equatorial 0-benzyl groups, whereas the reagent attacks mainly the equatorial oxygen atom of the dioxolane ring of the endo-isomers, giving a derivative containing equatorial hydroxyl and axial 0-benzyl groups. For example, benzyl exo- and endo-2,3-0-benzylidene-a-~-rhamnopyranoside gave benzyl 3- and 2-O-benzyl-ol-~-rhamnopyranosidein the ratio of 98 : 2 and 2 : 98, respectively, on hydrogenolytic ring-cleavage.