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The disadvantage of detritiation by oxidation into tritiated water is that at high temperatures radiolysis phenomena with air are greater thus leading to nitric acid formation at a pH of around 3-4. This tritiated and acid medium induces corrosion of stainless steel in the installations. 4. Material for the first containment The materials for the first containment of tritium must be chosen very carefully. The important parameters influencing the choice include tritium solubility, permeability, bakeability, strength, corrosion behavior, stress fatigue and tritium and helium embrittlement.
Absorption on mole- - - - cular sieves at very low water vapor pressure and room temperature is a widely used method but requires sieve regeneration by heating. a second recombiner of, for example, CuO, to oxidize the remaining tritium at 500°C. The global oxidation factor is approximately lo6. a cooler for control of minimum tritiated humidity. This unit decreases gas humidity to a dew point of -20°C to maintain the total detritiation factor about lo6. Moreover, cold trapping of tritiated water instead of second absorption on the molecular-sieve bed unit would decrease the amount of tritiated solid wastes and facilitate the tritiated water recovery.
With a view to reprocessing the organic products originating in the tritium facilities, an industrial unit was developed (Fig. 13) and constructed for specific treatment and packaging of such products so they were not considered as final waste [IS]. Decontamination is based on a drying process using steam, which results in a decontamination factor of 80%. Furthermore, the volume of the products to be stored is reduced by a factor of 8 by waste compaction. This industrial unit also cuts down the degassing rates of the stored wastes, which allows placing them in 'cold' sites, thus significantly reducing costs and providing an economic advantage to the management of tritiated wastes.