By Thomas J. Cogdell (Auth.)
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Additional resources for Student's Solutions Manual to Accompany Organic Chemistry
CH3CH—CH(CH ) CH~ II OH z CH 3 -> CH-C—CH(CH 9 ) ΓΗ, 3 II I 0 CH^ 61 Student Solutions Manual for Organic Chemistry Other structures are possible. CiCH ) CH , would be achiral.
4-2 K) // x=l· Cl v I /CH3 >^(, I / CH 2 C1 >κ χ Chapter Four D D-1 D-2 52 D-3 A, B, and C, are all constitutional isomers with respect to everything else. D and D-1 are enantiomers and each is a diastereomer of D-2 and D-3. D-2 and D-3 are also enantiomers. 4-3 a. achiral b. achiral and the cord is included) c. d. chiral chiral (assuming it is a common desk phone e. achiral and an American car are enantiomeric designs) f. chiral (an English car g. chiral h. chiral (they do make left-handed scissors) 4-4 a.
H b. Br c. 9 d. H - y\ ->==3H -cl C1C^< H, cic^\ /\ Br \ two planes 4-5 no plane a. plane of symmetry b. plane of symmetry and center of symmetry c. no symmetry element 4-6 Achiral: a, b, c, e, g, i Chiral centers are underlined in the following molecules: CH. CH3CH CHCH CH CH f. C1CH CHC1CH NH, CH CHCOOH ·Η y-=^n 53 4-7 Student Solutions Manual for Organic Chemistry a. Methylcyclopentane is achiral because it lacks a chiral center. b. cis-1,3-Dimethylcyclopentane is meso. c. 2,3-Dimethylpentane is chiral, but not identically substituted at its two chiral centers.